2,4-Dimethyl-N-(2-methyl­phen­yl)benzene­sulfonamide

نویسندگان

  • P. G. Nirmala
  • B. Thimme Gowda
  • Sabine Foro
  • Hartmut Fuess
چکیده

In the title compound, C(15)H(17)NO(2)S, the mol-ecule is bent at the S atom with a C-SO(2)-NH-C torsion angle of 71.6 (1)°. The two benzene rings are tilted by 47.0 (1)° relative to each other. The crystal structure features inversion-related dimers linked by pairs of N-H⋯O hydrogen bonds.

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منابع مشابه

2,4-Dimethyl-N-(3-methyl­phen­yl)benzene­sulfonamide

In the structure of the title compound, C(15)H(17)NO(2)S, the dihedral angle between the two aromatic rings is 47.1 (1)°. In the crystal structure, mol-ecules are connected by N-H⋯O hydrogen bonds, forming C(4) chains running along the c axis.

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2,4-Dimethyl-N-(4-methyl­phen­yl)benzene­sulfonamide

The asymmetric unit of the crystal of the title compound, C(15)H(17)NO(2)S, contains two independent mol-ecules, which are twisted at the S-N bonds with C-SO(2)-NH-C torsion angles of 48.3 (2) (mol-ecule 1) and -75.7 (3)° (mol-ecule 2). The dihedral angles between the benzene rings are 72.0 (1) (mol-ecule 1) and 78.3 (1)° (mol-ecule 2). The crystal structure features inversion dimers linked by ...

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2,4-Dichloro-N-(3-methyl­phen­yl)benzene­sulfonamide

In the title compound, C(13)H(11)Cl(2)NO(2)S, the conformations of the N-C bonds in the C-SO(2)-NH-C segments have gauche torsions with respect to the S=O bonds. The dihedral angle between the two benzene rings is 68.6 (1)°. The crystal structure features inversion dimers linked by pairs of N-H⋯O hydrogen bonds.

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2,4-Dichloro-N-(2-methyl­phen­yl)benzene­sulfonamide

In the title compound, C(13)H(11)Cl(2)NO(2)S, the methyl-substituted aromatic ring is disordered over two positions [occupancy ratio 0.705 (5):0.295 (5)]. The dihedral angles between the two aromatic rings are 74.9 (1) and 71.0 (3)° in the two disorder components. The crystal structure features centrosymmetric dimers linked by pairs of N-H⋯O hydrogen bonds.

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2,4-Dichloro-N-(4-methyl­phen­yl)benzene­sulfonamide

The title compound, C(13)H(11)Cl(2)NO(2)S, crystallizes with four independent mol-ecules in the asymmetric unit. In each of the four mol-ecules, the conformation of the N-C bond in the C-SO(2)-NH-C segment is gauche with respect to both S=O bonds. The mol-ecules are twisted at the S-N bonds with C-SO(2)-NH-C torsion angles of 60.6 (4), -59.7 (3), 63.9 (4) and 53.0 (4)°. The benzene rings in two...

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عنوان ژورنال:

دوره 65  شماره 

صفحات  -

تاریخ انتشار 2009